Heat oven to 375°F. With 1 tablespoon butter, generously butter bottom and sides of 9-inch round cake pan. Spread ice cream topping in buttered pan. Sprinkle with pecans and orange peel. Place frozen biscuits over pecans and orange peel.
Bake at 375°F. for 25 to 28 minutes or until golden brown and biscuits are no longer doughy. Immediately invert on serving platter; spread any topping remaining in pan over biscuits. Serve warm.