Spray 4- to 5-quart slow cooker with cooking spray. In cooker, place chicken.
In medium bowl, mix pasta sauce, wine, tomato paste, sugar, dried basil, mushrooms and bell pepper; spoon over chicken.
Cover; cook on Low heat setting 7 to 9 hours.
About 15 minutes before serving, cook pasta as directed on package. Transfer chicken mixture to large serving bowl or deep platter. Serve with pasta. Garnish with cheese and fresh basil.